What is the correct order of trans effect?
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What is the correct order of trans effect?
Trans effect : The intensity of trans effect depend on increase in rate of substitution of the trans ligand. F-
What is trans effect class 12?
Hint: We need to remember that in simple words trans effect is the position that an incoming ligand will attach to a square planar complex or it is the effect of ligand towards the substitution on another ligand which is trans to it. It is a process of labialization which means formation of more reactive ligands.
Which of the following correctly place the ligands in their order in the trans effect series?
The order of ligands in decreasing trans-directing power is:CN− > NO2 > I− > Br− > Cl− > NH3 > H2O.
Which statement about the trans effect and the trans influence is correct?
Which statement about the trans-effect and trans-influence is correct? a. The trans-influence is a ground state effect, whereas the trans-effect has a kinetic origin b. The trans-effect is a ground state effect, whereas the trans-influence has a kinetic origin c.
Which of the following is the theory of trans effect?
There are two main theories which can explain the phenomenon of trans effect. According to this theory the polarization (effect of σ-bonding) of a ligand would be directly related to its Trans effect. In case of [Pt(X)4] type complex, the overall dipole generated are zero, hence no trans effect are observed.
Which series correctly places the ligands in order of increasing Nephelauxetic effect?
The nephelauxetic effect does not only depend upon the ligand type, but also upon the central metal ion. These too can be arranged in order of increasing nephelauxetic effect as follows: Mn(II) < Ni(II) ≈ Co(II) < Mo(II) < Re(IV) < Fe(III) < Ir(III) < Co(III) < Mn(IV)
What theory explains trans effect?
What is trans effect for NEET?
Trans effect can be defined as the effect of a ligand towards substitution on other ligand which is trans to it.
What is trans effect ligands?
In inorganic chemistry, the trans effect is the increased lability of ligands that are trans to certain other ligands, which can thus be regarded as trans-directing ligands. The discovery of the trans effect is attributed to Ilya Ilich Chernyaev, who recognized it and gave it a name in 1926.
What is trans effect discuss polarization theory of trans effect?
the planner complex is called the trans effect. • The Trans effect of the ligands which are not able to form metal-ligand π-bonds, increases with the increase of their polarisability. • The Trans directing ability of the π-bonding ligands increases with the increase of. their ability to form metal–ligand π-bond.
What is meant by trans effect?
From Wikipedia, the free encyclopedia. In inorganic chemistry, the trans effect is the increased lability of ligands that are trans to certain other ligands, which can thus be regarded as trans-directing ligands.
What is the difference between trans effect and trans influence?
The key word in that last sentence is “rate”—the trans effect proper is a kinetic effect. The trans influence refers to the impact of a ligand on the length of the bond trans to it in the ground state of a complex.