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Which is more basic ortho para or meta?

Which is more basic ortho para or meta?

Look at the three amines below: ortho- (1,2), meta- (1,3), and para- (1,4) nitroaniline. Thus we’d expect the para isomer to be the most basic, since it has the maximum distance between NH2 and NO2, and the ortho isomer should be the least basic since it’s closest to the nitro group.

Which compound is the least basic * 1 point para methoxy aniline para amino aniline Ortho amino aniline para nitro aniline?

The correct increasing order of basic strength for the following compounds is H5​NHC2​H5​

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Which is more basic methyl aniline or methoxy aniline?

In aniline, p-methoxyaniline and p-methyl aniline, the lone pair of electrons on the Natom is delocalised on the benzene ring while in benzylamine it is delocalised, and more available for donation. Hence benzylamine is most basic among the given.

Which is more basic aniline or ortho nitroaniline?

Electron donating group increases basic strength whereas electron withdrawing group decreases basic strength of aniline. For example, o-methyl aniline is more basic than aniline and o-nitro aniline is less basic than aniline.

Why ortho methoxy aniline is more basic than meta methoxy aniline?

The m-methoxy group removes electron density from nitrogen by -I effect, making it less basic than aniline. The basicity of o-methoxy aniline is controlled by a mix of resonance and inductive effects operating in opposite directions. And its lesser basic character can be better understood by SIP or ortho effects.

Why Para is more basic than meta?

As the CH₃ groups shifts electrons towards the benzene ring from para position in p-toluidine, the electron density of the ring increases, and so te lone pair of N is readily available, which makes it a good base than m-toluidine, in which the CH₃ group attached in meta position cannot show +I effect strongly, and the …

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Why is meta nitroaniline more basic than para nitroaniline?

In the o-nitroaniline and p-nitroaniline compound, delocalization of the lone pair is observed. Therefore, o-nitroaniline is less basic than p-nitroaniline compounds. In m-nitroaniline only inductive effect is observed and therefore, it is more basic compared to others.

Why para methoxy aniline is more basic than aniline?

Methoxy group (-OCH3) is electron releasing group and increases the electron density on N atom. Therefore, it has greater electron donating tendency than aniline and thus is a stronger base than aniline.

Why Meta nitroaniline is more basic than ortho and para nitroaniline?

Which is more basic aniline or para chloroaniline?

Methyl groups make aniline a stronger base, while chloro or nitro groups make aniline a weaker base. For comparison, the pKb of aniline is 9.38.

Which is more basic meta toluidine or para toluidine?