Questions

What is the difference between Raman spectroscopy and FTIR?

What is the difference between Raman spectroscopy and FTIR?

The key difference between FTIR and Raman spectroscopy is that FTIR technique measures how much light is remaining from the original light from the light source, whereas Raman spectroscopy measures the energy that scatters after being excited by a laser.

Which is better Raman or FTIR?

The key advantage of Raman spectroscopy is that it requires little to no sample preparation while the FTIR method has constraints on sample thickness, uniformity and dilution to avoid saturation. The key advantage to FTIR is the difference of the two methods in dealing with interference.

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What is FT-Raman?

The FT-Raman spectroscopy is a specific Raman configuration designed to collect fluorescence-free and wavelength-stable measurements from a wide range of samples, spanning from crystals to biological tissues (Hirschfeld and Chase, 1986).

How Raman spectroscopy is different from other spectroscopy?

Raman spectra result from scattering of light by vibrating molecules whereas IR spectra result from light absorption by vibrating molecules. Raman activity results from change of polarizability of a molecule whereas IR activity results from changing dipole moment. This results in higher cost of the Raman spectrometer.

What is the basic advantage of FTIR over conventional IR with a monochromator explain?

Whereas a conventional scanning spectrophotometer that uses a monochromator takes several minutes to scan through the wavelengths, the mirror movement in an FT-IR occurs over a few seconds. Another advantage is that an FT-IR has no slits and therefore has a high throughput of radiation.

What is the major advantage of FTIR over dispersive IR instruments?

The FT-IR advantage is that many scans can be completed and combined on an FT-IR in a shorter time than one scan on a dispersive instrument. The multiplex advantage results in faster data collection of an FT-IR spectrum.

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What are the advantages of Raman over IR spectroscopy in molecular structural identification?

Raman spectroscopy yields information about intra- and inter- molecular vibrations. Infrared spectroscopy’s greatest value lies in its ability to probe the so-called “fingerprint region” of the spectrum where intramolecular vibrations are well-defined and highly characteristic of the bonding of atoms.

What are the limitations of Raman Spectroscopy?

Disadvatantages of Raman Spectroscopy

  • can not be used for metals or alloys.
  • the Raman effect is very weak.
  • fluorescence of impurities or of the sample itself can hide the Raman spectrum.
  • sample heating through the intense laser radiation can destroy the sample or cover the Raman spectrum.

How Raman effect is used in Raman Spectroscopy?

RAMAN SPECTROSCOPY. The Raman effect involves scattering of light by molecules of gases, liquids, or solids. The Raman effect consists of the appearance of extra spectral lines near the wavelength of the incident light. The Raman lines in the scattered light are weaker than the light at the original wavelength.

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What does Raman spectroscopy tell you?

Raman Spectroscopy is a non-destructive chemical analysis technique which provides detailed information about chemical structure, phase and polymorphy, crystallinity and molecular interactions. It is based upon the interaction of light with the chemical bonds within a material.