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Why is a buffer considered effective over a range of 1 pH unit above or below its pKa?

Why is a buffer considered effective over a range of 1 pH unit above or below its pKa?

Popular Answers (1) The ability of a buffer solution to maintain a nearly constant pH when a small amount of acid or base is added to the solution is greatest at the pKa and diminishes as the pH of the solution goes above or below the pKa.

Why is a buffer only effective within a certain pH range?

This is due to the change that occurs when another acid or base is added to the buffer. The change is minimized if the concentrations of acid and conjugate base are equal. The more the ratio needs to differ to achieve the desired pH, the less effective the buffer.

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What is the range of a buffer?

The buffer range is the pH range where a buffer effectively neutralizes added acids and bases, while maintaining a relatively constant pH.

What is the effective pH range of a buffer relative to the pKa of the weak acid component )?

What is the effective pH of a buffer (relative to the pKa of the weak acid component)? The pH should be within one pH unit of the weak acid’s pKa, meaning that the concentrations of the acids and bases should not differ by more than a factor of 10.

What is the effective buffering range for acetic acid acetate buffer?

3.7 to 5.7
For acetate buffer, the pKa value of acetic acid is equal to 4.7 so that getting pKa±1 , the buffer is suitable for a pH range of 4.7±1 or from 3.7 to 5.7.

Which buffer will have the greatest buffer capacity?

The value of the buffer capacity is strongly related to the concentrations of ingredients used and increases with their increase. Buffer solutions with a pH equal to the pKa value of the acid (used to make this solution) have the greatest buffering capacity.

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What is the effective pH range of a buffer relative to the pKa pKa of the weak acid component )?

What is the pH range of most buffer systems pKa?

An ideal buffering system has a pKa of ~ 7.4 (normal physiologic pH). Bicarbonate has a pKa of 6.1, which is NOT ideal in normal physiologic conditions. In fact, the pH range of effectiveness is probably ~ 5.1 – 7.1 for the bicarbonate buffer system.

What is the pH of a buffer solution when the concentrations of both buffer components the weak acid and its conjugate base are equal?

A solution that contains a weak acid and its conjugate base in comparable amounts, not necessarily in equal amounts, is called a buffer solution. As you can see here, equal amounts of weak acid and of conjugate base will make the log term equal to zero, and thus the pH equal to the pKa .