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Why phenol is a weaker acid?

Why phenol is a weaker acid?

Phenol is a very weak acid and the position of equilibrium lies well to the left. Phenol can lose a hydrogen ion because the phenoxide ion formed is stabilised to some extent. The negative charge on the oxygen atom is delocalised around the ring. That is why phenol is only a very weak acid.

Is phenol more or less acidic than carboxylic acid?

Phenol Answers Carboxylic acids (pKa»5) are more acidic than phenols (pKa»10) which in turn are more acidic than simple alcohols (pKa»16 – 20). The carboxylate anion is stabilised by resonance that allows the negative charge to be delocalised onto a second electronegative oxygen atom.

Why are carboxylic acids stronger than alcohols and phenols?

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Carboxylic acids are more acidic than alcohols or phenols, although all of them have a hydrogen atom attached to an oxygen atom (—O—H) because the conjugate base of carboxylic acids or the carboxylate ion is stabilized by resonance. Thus, carboxylic acids can release proton easier than alcohols or phenols.

Why do carboxylic acids act as weak acids?

Carboxylic acids are weak acids because they only partially ionise in solution. Their solutions do not contain many hydrogen ions compared to a solution of a strong acid at the same concentration. In a solution of strong acid, the molecules are fully ionised. In a weak acid, few of the molecules are ionised.

Why are aliphatic carboxylic acid stronger than phenol?

in case of phenols, negative charge is less effectively delocalized over one oxygen atom and less electronegative carbon atoms in phenoxide ion. Therefore, the carboxylate ion exhibits higher stability in comparison to phenoxide ion. Hence, the carboxylic acids are more acidic than phenols.

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Why are carboxylic acids are stronger acids than alcohols?

The stability of an anion determines the strength of its parent acid. A carboxylic acid is, therefore, a much stronger acid than the corresponding alcohol, because, when it loses its proton, a more stable ion results.

Why carboxylic acids are weak acids?

Carboxylic acids are weak acids because they only partially ionise in solution. Their solutions do not contain many hydrogen ions compared to a solution of a strong acid at the same concentration. In a weak acid, few of the molecules are ionised.

Why are carboxylic acids more stronger than alcohols?

How is phenol distinguished from carboxylic acid?

By NaHCO solution test : Phenol does not react with NaHCO3 solution but carboxylic acid gives brisk effervescence due to formation of CO2.